Changes in hydrogen storage properties of carbon nano-horns submitted to thermal oxidation

The effect of thermal oxidation on the hydrogen storage properties of carbon nano-horns was investigated by gravimetric and electrochemical methods. The pristine nano-horn sample was oxidised at 673 K in air for different periods (15, 30 and 60 min) and the resulting materials were characterised. The N₂ adsorption experiments reveal a marked increase in the surface area, from 267 m² g⁻¹, for the pristine sample, up to 1360 m² g⁻¹ for the sample oxidised for the 60 min period, and a reduction in the average pore diameter. The gravimetric investigation, conducted at low temperature (77 K) showed an increase in the hydrogen storage, from 0.75 wt% for the pristine sample up to 2.60 wt% for the oxidised material. Reproducible and stable hydrogen storage was found for all the samples examined apart from the sample oxidised for 60 min. For the latter, a decrease in the amount of hydrogen stored between the first and second cycles was found. Electrochemical loading of hydrogen in the samples was performed at room temperature (298 K) in alkaline solution by the galvanostatic charge/discharge technique. The results obtained here however show a much lower hydrogen storage level by the samples as compared to the gas storage method, with a maximum value of 0.124 wt% H₂ and with very little dependence on the thermal oxidation treatment.     

Coarsening of a multimodal nickel-base superalloy

The coarsening of γ′-Ni₃Al precipitates in the nickel superalloy Ni115 has been examined and compared to the results of a numerical model based on LSW coarsening theory. Ni115 has a γ′ fraction of around 60%, and at the coarsening temperatures of interest the γ′ distribution is bimodal, with two populations ～5 nm and ～90 nm in radius. It is found that during the initial transient (around 2000 h at 800 °C), the fine γ′ dissolve, leading to a rapid increase in the mean radius followed by a plateau. At long times, the expected steady-state unimodal t^1/3 coarsening is observed. The model reproduces these features in form and approximately in magnitude, a first for LSW model-experiment comparisons in nickel superalloys.     

An investment-led approach to analysing the hydrogen energy economy in the UK

The authors propose an alternative, investment-led approach to analysing the potential for the development of hydrogen energy in the UK. The UK economy is relatively sensitive to movements in world fossil fuels markets since the energy sector contributes at least 5% of UK GDP and represents an asset pool of at least £230 billion. Much of the ongoing research to assess possible scenarios for the development of alternatives to existing energy systems, including hydrogen energy, in the UK is built around the cost-optimising MARKAL model. The authors believe that this approach offers an incomplete picture of hydrogen energy deployment since it ignores the mechanisms dictating the flow of commercial capital to the sector and they suggest an alternative model based on the risk-adjusted value proposition. Initial analysis shows that valuation differentials already exist between companies in the fossil fuel, utilities and fuel cell sectors and that this might be exploited to the advantage of investors thus affecting the speed of development in hydrogen energy. It should be noted that the following represents work in progress and the authors intend to publish an extended analysis in due course.     

Compressibility and rarefaction effect on heat transfer in rough microchannels

High pressure drop and high length to hydraulic diameter ratios yield significant compressibility effects in microchannel flows, which compete with rarefaction phenomena at the smaller scale. In such regimes, flow field and temperature field are no longer decoupled. In presence of significant heat transfer, and combined with the effect of viscous dissipation, this yields to a quite complex thermo-fluid dynamic problem. A finite volume compressible solver, including generalized Maxwell slip flow and temperature jump boundary conditions suitable for arbitrary geometries, is adopted. Roughness geometry is modeled as a series of triangular shaped obstructions, and relative roughness from 0% to 2.65% were considered. The chosen geometry allows for direct comparison with pressure drop computations carried out, in a previous paper, under adiabatic conditions. A wide range of Mach number is considered, from nearly incompressible to chocked flow conditions. Flow conditions with Reynolds number up to around 300 were computed. The outlet Knudsen number corresponding to the chosen range of Mach and Reynolds number ranges from very low value to around 0.05, and the competing effects of rarefaction, compressibility and roughness are investigated in detail. Compressibility is found to be the most dominant effect at high Mach number, yielding even inversion of heat flux, while roughness has a strong effect in the case of rarefied flow. Furthermore, the mutual interaction between heat transfer and pressure drop is highlighted, comparing Poiseuille number values for both cooled and heated flows with previous adiabatic computations.     

Application of a duplex diffusion layer model to pulse reverse plating

The application of Ibl’s duplex diffusion layer model to the analysis of mass transport in pulse reverse plating with bipolar current pulses has been investigated. Although originally proposed to describe normal pulse plating, Yin has recently extended Ibl’s model to include pulse reverse plating. Using the expressions derived by Yin the pulse limiting current density was determined over a wide range of pulse plating conditions, and then compared to values calculated using more accurate numerical solutions. In general, there was good agreement between the two approaches which demonstrated the essential validity of Yin’s extension to Ibl’s original model. The simplified model is most accurate at long duty cycles, small dimensionless pulse times and for low values of the dimensionless pulse reverse current where its underlying assumptions are most likely to be valid. At very long dimensionless pulse times (i.e. T*?>?1) the model becomes increasingly inaccurate and its use in these circumstances cannot be justified.     

Rapid fabrication of function-structure-integrated NiTi alloys: Towards a combination of excellent superelasticity and favorable bioactivity

Porous NiTi has brought new expectations to the field of orthopaedic implants due to its excellent mechanical properties such as high strength and superelasticity together with good biocompatibility. In order to facilitate the surrounding bone tissue ingrowth into the implanted porous alloy, reasonably large sized pores and a high amount of porosity are required. There is, however, a major challenge for clinical applications: the higher the porosity, the worse are the mechanical properties and the superelasticity. In this work, therefore, function-structure-integrated NiTi alloys consisting of a central solid and an outer porous layer were fabricated by spark plasma sintering (SPS). When sintered at 750 °C, the NiTi alloy with 14% porosity in the inner part and 49% porosity as well as 350 μm average pore size in the outer layer exhibits an exceptionally high compressive strength (∼1375 MPa), together with an excellent superelastic recovery strain (>4%) and favorable cellular affinity (ROS1728 osteoblasts). Altogether, this work provides a strategy to design materials with function-structure integration and suggests that properly designed function-structure integrated NiTi alloys may be promising as advanced bone implants.     

Low‐cost mounting arrangements for building‐integrated wind turbines

Micro‐generation is being widely promoted as a way for householders in the UK and elsewhere to take part in ‘the Green Revolution’. Building‐integrated wind turbines (BIWTs) provide a way to do this, enabling people to reduce their contribution to the problems of both climate change and decreasing fossil fuel availability. Although energy yields from BIWTs for many householders have been shown to be low, there are still situations where such turbines can make a useful contribution to electricity generation, e.g. in windier areas and for isolated detached buildings. The standards for the installation of BIWTs are still being developed including those for the safe mounting of turbines on domestic buildings. This paper investigates the current trend for mounting small wind turbines on the walls of domestic premises and compares this with an approach which uses roof timbers. It identifies the main characteristics of building construction which affect the integrity of such installations. European and British standards have been used to calculate wind and gravitational loads. Finite element models are used to derive working stresses and, hence, some basic principles of good design. The likely costs of wall and roof mounting are then compared. Installation and health and safety issues are also examined briefly. Copyright © 2010 John Wiley & Sons, Ltd.     

Improved fracture toughness of carbon fibre/epoxy composite laminates using dissolvable thermoplastic fibres

This paper reports on a novel toughening concept based on dissolvable phenoxy fibres, which are added at the interlaminar region in a carbon fibre/epoxy composite. The composites were prepared by resin infusion of carbon fibre fabric with the phenoxy introduced as a chopped fibre interleaf between the carbon fibre plies. The thermoplastic phenoxy fibre dissolved in the epoxy during curing at elevated temperatures and a phase separated morphology with phenoxy-rich secondary phase was formed upon curing. It was found that the average Mode-I fracture toughness value, G_1c increased tenfold with only 10 wt.% (with regard to the total matrix content) phenoxy fibre added. Other properties such as Young’s modulus, tensile strength and thermal stability were not adversely affected. The mechanical and thermal properties of the neat epoxy–phenoxy blends were also studied for comparison.     

Linear Matching Method for Design Limits in Plasticity

In this paper a state-of-the-art numerical method is discussed for the evaluation of the shakedown and ratchet limits for an elastic-perfectly plastic body subjected to cyclic thermal and mechanical load history. The limit load or collapse load, i.e. the load carrying capacity, is also determined as a special case of shakedown analysis. These design limits in plasticity have been solved by characterizing the steady cyclic state using a general cyclic minimum theorem. For a prescribed class of kinematically admissible inelastic strain rate histories, the minimum of the functional for these design limits are found by a programming method, the Linear Matching Method (LMM), which converges to the least upper bound. By ensuring that both equilibrium and compatibility are satisfied at each stage, a direct algorithm has also been derived to determine the lower bound of shakedown and ratchet limit using the best residual stress calculated during the LMM procedure. Three practical examples of the LMM are provided to confirm the efficiency and effectiveness of the method: the behaviour of a complex 3D tubeplate in a typical AGR superheater header, the behaviour of a fiber reinforced metal matrix composite under loading and thermal cycling conditions, and effects of drilling holes on the ratchet limit and crack tip plastic strain range for a centre cracked plate subjected to constant tensile loading and cyclic bending moment.